Cyclohexene → HCID 19751984, compound

HRID 2051057Notes

Reaction equation

HRID 2051057 reaction equation
[N+:1]([C:4]1[C:5]([O:16][CH3:17])=[C:6]([Cl:15])[CH:7]=[C:8]([N+:12]([O-])=O)[C:9]=1[O:10][CH3:11])([O-:3])=[O:2].C1CCCCC=1>[Pd].C(O)C>[NH2:12][C:8]1[C:9]([O:10][CH3:11])=[C:4]([N+:1]([O-:3])=[O:2])[C:5]([O:16][CH3:17])=[C:6]([Cl:15])[CH:7]=1

Participants

5

Reactant 2

HCID 8079CyclohexeneHCID 2849581-chloro-2,4-dimethoxy-3,5-dinitrobenzene

Product 1

HCID 19751984HCID 19751984, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

A mixture consisting of 0.2 mole (52.5 g) of 3,5-dinitro-2,4-dimethoxychlorobenzene and 15.9 g of palladium on charcoal (10%) in 260 ml of absolute ethanol containing 110 ml of cyclohexene was heated to reflux for 1 hour.

Workup

  1. temperaturewas heated
  2. temperatureto reflux for 1 hour

Sources & evidence

ORD record
ord-d1c4ac1468ad4b0cb73c95bd3afaf48b
Source dataset
uspto-grants-1991_05
Patent number
US05015772

Reaction notes

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