HCID 19979416, compound → HCID 19834295, compound

HRID 2051078Notes

Reaction equation

HRID 2051078 reaction equation
[C:1]([O:23][CH:24]1[CH2:29][C:28]([CH3:31])([CH3:30])[N:27]([OH:32])[C:26]([CH3:34])([CH3:33])[CH2:25]1)(=[O:22])[C:2]1[CH:21]=[CH:20][CH:19]=[C:4]([C:5]([O:7][CH:8]2[CH2:13][C:12]([CH3:15])([CH3:14])[N:11]([OH:16])[C:10]([CH3:18])([CH3:17])[CH2:9]2)=[O:6])[CH:3]=1.[C:35]([O:39][CH:40]1[CH2:45][C:44]([CH3:47])([CH3:46])[N:43]([O:48][CH3:49])[C:42]([CH3:51])([CH3:50])[CH2:41]1)(=[O:38])[CH:36]=[CH2:37]>>[C:5]([O:7][CH:8]1[CH2:13][C:12]([CH3:14])([CH3:15])[N:11]([O:16][CH2:37][CH2:36][C:35]([O:39][CH:40]2[CH2:41][C:42]([CH3:50])([CH3:51])[N:43]([O:48][CH3:49])[C:44]([CH3:46])([CH3:47])[CH2:45]2)=[O:38])[C:10]([CH3:18])([CH3:17])[CH2:9]1)(=[O:6])[C:4]1[CH:19]=[CH:20][CH:21]=[C:2]([C:1]([O:23][CH:24]2[CH2:25][C:26]([CH3:34])([CH3:33])[N:27]([O:32][CH2:37][CH2:36][C:35]([O:39][CH:40]3[CH2:41][C:42]([CH3:51])([CH3:50])[N:43]([O:48][CH3:49])[C:44]([CH3:46])([CH3:47])[CH2:45]3)=[O:38])[C:28]([CH3:31])([CH3:30])[CH2:29]2)=[O:22])[CH:3]=1

Participants

3

Reactant 2

HCID 19979416HCID 19979416, compoundHCID 54511513HCID 54511513, compound

Product 1

HCID 19834295HCID 19834295, compoundYield 31%

Procedure

The title compound is prepared in a 31% yield as a colorless glass from bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl) isophthalate and 1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl acrylate according to the general procedure of Example 12. The reaction is reduced from five days to 48 hours in this case.

Workup

  1. waitThe reaction is reduced from five days to 48 hours in this case

Sources & evidence

ORD record
ord-bec75d9d62054afea433c9fa2ae2ffa2
Source dataset
uspto-grants-1991_05
Patent number
US05015678

Reaction notes

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