Sulfuric Acid → Methyl 3-(1-adamantyl)-4-methoxybenzoate

HRID 2051083Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 2051083
C(O[C:5]12[CH2:14][CH:9]3[CH2:10][CH:11]([CH2:13][CH:7]([CH2:8]3)[CH2:6]1)[CH2:12]2)(=O)C.S(=O)(=O)(O)O.[CH3:20][O:21][C:22]1[CH:31]=[CH:30][C:25]([C:26]([O:28][CH3:29])=[O:27])=[CH:24][CH:23]=1>CCCCCCC>[C:5]12([C:23]3[CH:24]=[C:25]([CH:30]=[CH:31][C:22]=3[O:21][CH3:20])[C:26]([O:28][CH3:29])=[O:27])[CH2:12][CH:11]3[CH2:10][CH:9]([CH2:8][CH:7]([CH2:13]3)[CH2:6]1)[CH2:14]2

Komponenten

5

Edukt 3

HCID 1118Sulfuric AcidHCID 8499Methyl anisateHCID 5199731-Adamantyl acetate

Produkt 1

HCID 14549070Methyl 3-(1-adamantyl)-4-methoxybenzoate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8900HeptaneLösungsmittel

Versuchsvorschrift

In a 100 ml three-necked flask, under a nitrogen environment, are placed 2 g of 1-acetoxyadamantane and 20 ml of n-heptane. After total dissolution, 0.5 g of concentrated sulfuric acid is added drop by drop. At a temperature of approximately 20.C, 1.71 g of methyl 4-methoxybenzoate is added slowly and agitated for 48 hours. The solid obtained is filtered with sintered glass and washed with water until neutrality is reached. After drying in a vacuum oven for 24 hours at 25 C, one recovered 2 g of expected raw product (Melting point: 136°-137° C.).

Aufarbeitung

  1. customIn a 100 ml three-necked flask, under a nitrogen environment, are placed
  2. additionis added drop by drop
  3. customThe solid obtained
  4. filtrationis filtered with sintered glass
  5. washwashed with water until neutrality
  6. customAfter drying in a vacuum oven for 24 hours at 25 C, one
  7. customrecovered 2 g of expected raw product (Melting point: 136°-137° C.)

Quellen und Nachweise

ORD-Eintrag
ord-94f7db431322401fb3b196eda1357ee8
Quelldatensatz
uspto-grants-1991_05
Patentnummer
US05015758

Notizen zur Reaktion

Wird geladen…