HCID 131716895, compound → HCID 131716894, compound

HRID 2051244Notes

Reaction equation

Cl/C(/C(F)(F)F)=C\[C@@H]1[C@H](C(OCC2C(F)=C(F)C(CC=CBr)=C(F)C=2F)=O)C1(C)C.[Cl:31]/[C:32](/[C:58]([F:61])([F:60])[F:59])=[CH:33]\[C@@H:34]1[C@H:36]([C:37]([O:39][CH2:40][C:41]2[C:46]([F:47])=[C:45]([F:48])[C:44]([CH2:49][C:50](C)=[CH:51][Cl:52])=[C:43]([F:54])[C:42]=2[F:55])=[O:38])[C:35]1([CH3:57])[CH3:56]>>[Cl:31]/[C:32](/[C:58]([F:59])([F:60])[F:61])=[CH:33]\[C@@H:34]1[C@H:36]([C:37]([O:39][CH2:40][C:41]2[C:42]([F:55])=[C:43]([F:54])[C:44]([CH2:49]/[CH:50]=[CH:51]/[Cl:52])=[C:45]([F:48])[C:46]=2[F:47])=[O:38])[C:35]1([CH3:57])[CH3:56]

Participants

Reactant 2

HCID 131716895HCID 131716895, compound2×

HCID 131716896HCID 131716896, compound2×

Product 1

HCID 131716894HCID 131716894, compound

Procedure

4-(EZ-3-bromoprop-2-en-1-yl)-2,3,5,6-tetrafluorobenzyl (±)-cis-3-(Z-2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropanecarboxylate (E:Z ratio of alcohol moiety 3:1, Product VII) 4-(EZ-3-chloro-2-methylprop-2-en-1-yl)-2,3,5,6-tetrafluorobenzyl (±)-cis-3-(Z-2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropanecarboxylate (E:Z ratio of alcohol moiety 1:4, Product VIII)

Sources & evidence

ORD record: ord-5f8bd08b71ab498eb2d89417b796d45f
Source dataset: uspto-grants-1991_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05017606

Reaction notes

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