Sodium Carbonate → HCID 178468160, compound

HRID 2051600Notes

Reaction equation

HRID 2051600 reaction equation
C(=O)([O-])[O-].[Na+].[Na+].[C:7]([C@H:10]1[CH2:15][CH2:14][C@@H:13]([C:16]([CH3:19])([CH3:18])[CH3:17])[CH2:12][CH2:11]1)(=[O:9])[CH3:8]>CO>[C:7]([C@H:10]1[CH2:15][CH2:14][C@H:13]([C:16]([CH3:19])([CH3:18])[CH3:17])[CH2:12][CH2:11]1)(=[O:9])[CH3:8]

Participants

4

Reactant 2

HCID 10340Sodium CarbonateHCID 178468159HCID 178468159, compound

Product 1

HCID 178468160HCID 178468160, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The cis isomer was epimerized in a refluxing solution of sodium carbonate in aqueous methanol to a 90%:10% mixture of trans:cis-1-acetyl-4-t-butylcyclohexane. The spectral data of this mixture was essentially identical with that obtained for the pure trans isomer.

Workup

  1. customthat obtained for the pure trans isomer

Sources & evidence

ORD record
ord-46908df13b204c6cbf54f16e8f6849db
Source dataset
uspto-grants-1980_01
Patent number
US04181631

Reaction notes

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