Isobutylamine → HCID 54371209, compound

HRID 2051846Notes

Reaction equation

HRID 2051846 reaction equation
O=[CH:2][C@@H:3]([C@H:5]([C@H:7]([CH2:9][OH:10])[OH:8])[OH:6])[OH:4].[CH2:11]([NH2:15])[CH:12]([CH3:14])[CH3:13].[Cl:16][CH2:17][CH2:18][N:19]=[C:20]=[O:21]>>[Cl:16][CH2:17][CH2:18][NH:19][C:20]([N:15]([CH2:11][CH:12]([CH3:14])[CH3:13])[CH:9]1[O:10][CH2:2][C@H:3]([OH:4])[C@H:5]([OH:6])[C@H:7]1[OH:8])=[O:21]

Participants

4

Reactant 3

HCID 6558IsobutylamineHCID 160352-Chloroethyl isocyanateHCID 5460291aldehydo-L-arabinose

Product 1

HCID 54371209HCID 54371209, compoundYield 69.2%

Procedure

3.0 g of L-arabinose, 1.8 g of isobutylamine and 2.5 g of 2-chloroethyl isocyanate are treated in the same manner as described in Example 5-(1). 4.3 g of 1-(2-chloroethyl)-3-isobutyl-3-L-arabinopyranosylurea are thereby obtained as colorless caramel.

Sources & evidence

ORD record
ord-26d9373e050846faba5368d1f24c16b9
Source dataset
uspto-grants-1980_01
Patent number
US04182757

Reaction notes

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