(+-)-alpha-Pinene → HCID 131711681, compound

HRID 2052228Notes

Reaction equation

HRID 2052228 reaction equation
[P:1]([OH:12])([O:7][CH2:8][CH2:9][CH2:10][CH3:11])[O:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH3:13][C:14]1[CH:19]2[C:20]([CH3:22])([CH3:21])[CH:17]([CH2:18]2)[CH2:16][CH:15]=1>>[CH:14]1([CH3:13])[CH:15]([P:1](=[O:12])([O:7][CH2:8][CH2:9][CH2:10][CH3:11])[O:2][CH2:3][CH2:4][CH2:5][CH3:6])[CH2:16][CH:17]([CH:20]([CH3:21])[CH3:22])[CH2:18][CH:19]1[P:1](=[O:12])([O:7][CH2:8][CH2:9][CH2:10][CH3:11])[O:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

3

Reactant 2

HCID 6654(+-)-alpha-PineneHCID 15739Phosphorus acid, dibutyl ester

Product 1

HCID 131711681HCID 131711681, compoundYield 69%

Procedure

Dibutyl hydrogen phosphite and α-pinene were reacted in substantially the same manner as reported in Example 3 to make the titled compound (69% theory yield). The NMR spectrum was in agreement with the expected structure.

Sources & evidence

ORD record
ord-77f0aa64a0464ee29e238a8c2d6949e7
Source dataset
uspto-grants-1980_01
Patent number
US04183879

Reaction notes

Loading…