HRID2052258

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID118986

3,4-Dichlorotoluene-alpha-thiol

C7H6Cl2S

结构：C[C@]12CC(=O)[C@H]3[C@@H](CCC4=CC(=O)C=C[C@@]43C)[C@@H]1CC[C@@H]2OS(C)(=O)=O

HCID56609103

未命名化合物

PRODUCTS

生成物

结构：C[C@]12CC(=O)[C@H]3[C@@H](CCC4=CC(=O)C=C[C@@]43C)[C@@H]1CC[C@H]2SCc1ccc(Cl)c(Cl)c1

HCID22809849

未命名化合物

PROCEDURE

实验过程

In a manner similar to that described in Example 1A, 3,4-dichlorobenzylmercaptan is reacted with 17β-methanesulfonyloxy-1,4-androstadiene-3,11-dione to obtain the title compound of this example; m.p.=131°-133° C.; [α]D26 +150° (CHCl3); λmaxMeOH 228 nm (ε=26,000).