HRID2052340

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C[Si](C)(C)OCCCCCCCC1C(C=CC(=O)COc2ccccc2)CCC12OCCO2

HCID57027912

未命名化合物

结构：CCCCCC(=O)C=CC1CCC2(OCCO2)C1CCCCCCCO[Si](C)(C)C

HCID57236021

未命名化合物

HCID86736798

未命名化合物

PRODUCTS

生成物

结构：CC(O)(C=CC1CCC2(OCCO2)C1CCCCCCCO[Si](C)(C)C)COc1ccccc1

HCID54213428

未命名化合物

PROCEDURE

实验过程

By proceeding in a similar manner to that hereinbefore described in Example 3(iii), but replacing the 6-(7-trimethylsiloxyheptyl)-7-(3-oxooct-1-enyl)-1,4-dioxaspiro[4,4]nonane used as starting material by the appropriate quantity of 6-(7-trimethylsiloxyheptyl)-7-(3-oxo-4-phenoxybut-1-enyl)-1,4-dioxaspiro[4,4]nonane, there was prepared 7-(3-hydroxy-3-methyl-4-phenoxybut-1-enyl)-6-(7-trimethylsiloxyheptyl-1,4-dioxaspiro[4,4]nonane.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e2a5143b4e764c4887ecdb1f9724390a
来源数据集: uspto-grants-1980_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04183870
来源说明: uspto-grants-1980_01

反应 SMILES

[CH3:1][Si:2]([CH3:30])([CH3:29])[O:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH:11]1[CH:19]([CH:20]=[CH:21][C:22](=[O:28])[CH2:23]CCCC)[CH2:18][CH2:17][C:12]21[O:16][CH2:15][CH2:14][O:13]2.C[Si](C)(C)OCCCCCCCC1C(C=CC(=O)[CH2:53][O:54][C:55]2[CH:60]=[CH:59][CH:58]=[CH:57][CH:56]=2)CCC21OCCO2.C[Si](C)(C)OCCCCCCCC1COC2(CCCC2)O1>>[OH:28][C:22]([CH3:23])([CH2:53][O:54][C:55]1[CH:60]=[CH:59][CH:58]=[CH:57][CH:56]=1)[CH:21]=[CH:20][CH:19]1[CH2:18][CH2:17][C:12]2([O:13][CH2:14][CH2:15][O:16]2)[CH:11]1[CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][O:3][Si:2]([CH3:30])([CH3:29])[CH3:1]