Sodium Carbonate → HCID 13340366, compound

HRID 2052473Notes

Reaction equation

HRID 2052473 reaction equation
[N+:1]([C:4]1[CH:18]=[CH:17][CH:16]=[CH:15][C:5]=1[CH2:6][NH:7][C@H:8]([C:12]([OH:14])=[O:13])[CH2:9][S:10][CH3:11])([O-])=O.[H][H].C(=O)([O-])[O-].[Na+].[Na+]>[Ni]>[NH2:1][C:4]1[CH:18]=[CH:17][CH:16]=[CH:15][C:5]=1[CH2:6][NH:7][C@H:8]([C:12]([OH:14])=[O:13])[CH2:9][S:10][CH3:11]

Participants

5

Reactant 3

HCID 10340Sodium CarbonateHCID 13340360HCID 13340360, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 13340366HCID 13340366, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

N-(2-amino-benzyl)-S-methyl-cysteine of the formula ##STR11## was prepared in analogy to Example 1 (b) by reducing N-(2-nitro-benzyl)-S-methyl-cysteine with hydrogen under pressure in the presence of sodium carbonate and Raney nickel. Melting point: 193° C.

Sources & evidence

ORD record
ord-ed9a5a329c9d46a0adc98114554699a5
Source dataset
uspto-grants-1980_01
Patent number
US04185114

Reaction notes

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