Ammonium Chloride → HCID 178511493, compound

HRID 2052545Notes

Reaction equation

HRID 2052545 reaction equation
[Mg+2:1].[Cl-].[Cl-].[Cl-].[NH4+:5].[Fe-4:6]([C:17]#[N:18])([C:15]#[N:16])([C:13]#[N:14])([C:11]#[N:12])([C:9]#[N:10])[C:7]#[N:8].[K+].[K+].[K+].[K+]>>[Fe-4:6]([C:15]#[N:16])([C:11]#[N:12])([C:7]#[N:8])([C:9]#[N:10])([C:13]#[N:14])[C:17]#[N:18].[NH4+:5].[Mg+2:1]

Participants

4

Reactant 3

HCID 25517Ammonium ChlorideHCID 5360315Magnesium ChlorideHCID 178511492HCID 178511492, compound

Product 1

HCID 178511493HCID 178511493, compound

Procedure

Aqueous solutions which contained stoichiometric proportions of MgCl2, ammonium chloride and potassium ferrocyanide, respectively, were united so as to produce magnesium-ammonium ferrocyanide. The complex salt was dried and 10 g thereof with a particle size of 2 mm was placed in a reactor, in which it was contacted at 320° C. under a pressure of 20 atmospheres gauge with a gas mixture of CO and H2 in a ratio by volume of 1:1. The issuing gas was removed at a constant rate of 20 normal liters/h. The reaction gas contained 15.9 volume % of CH4, 0.5 volume % of C2H4, 2.35 volume % of C2H6, 0.3 volume % of C3H6 and 0.77 volume % of C3H8. A further 19 g of higher liquid hydrocarbons were obtained within 22 hours.

Sources & evidence

ORD record
ord-8dd03bce6852419ca2b0c850fafa2bea
Source dataset
uspto-grants-1980_01
Patent number
US04186112

Reaction notes

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