Methanol → Methyl 5-bromofuran-2-carboxylate

HRID 2053163Notes

Reaction equation

HRID 2053163 reaction equation

[Br:1][C:2]1[O:6][C:5]([C:7]([OH:9])=[O:8])=[CH:4][CH:3]=1.[CH3:10]O>>[CH3:10][O:8][C:7]([C:5]1[O:6][C:2]([Br:1])=[CH:3][CH:4]=1)=[O:9]

Participants

3

Reactant 2

HCID 887Methanol

HCID 685115-Bromo-2-furanecarboxylic acid

Product 1

HCID 599633Methyl 5-bromofuran-2-carboxylate

Procedure

5-Bromo-furan-2-carboxylic acid (2 g, 10.5 mmol) was esterified with MeOH using Method B to give the title compound.

Sources & evidence

ORD record: ord-2e9a520f40d84ffd9862ac10a711ba02
Source dataset: uspto-grants-2008_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07326732B2

Reaction notes

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