HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromohexane → Phosphonium, hexyltriphenyl-, bromide (1:1)
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromohexane | HCID 8101 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Phosphonium, hexyltriphenyl-, bromide (1:1) | HCID 2724569 | — |
Reaction Steps
82.5 g n-hexyl bromide and 131.2 g triphenylphosphine were boiled under reflux for 35 h in 500 ml toluene. The solvent was distilled off, the residue was taken up in dichloromethane and 1 l diethyl ether was added. Crystallisation at −15° C. gave n-hexyltriphenylphosphonium bromide (3).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07332468B2 |
| Source dataset | uspto-grants-2008_02 |
| ORD ID | ord-2a1ec67b10154e789b48907a091bb67e |
| Source note | uspto-grants-2008_02 |