HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl triflate → Bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl triflate | HCID 9526 | — |
| Reactant | Iodonium, bis[4-(1,1-dimethylethyl)phenyl]-, acetate | HCID 21909498 | — |
| Solvent | tert-Butyl methyl ether | HCID 15413 | — |
| Product | Bis(4-tert-butylphenyl)iodonium trifluoromethanesulfonate | HCID 2734848 | 76% |
Reaction Steps
tert-Butyl methyl ether (5 ml) was added to bis(p-tert-butylphenyl)iodonium acetate (467 mg; 1 mmol) and methyl trifluoromethanesulfonate (170 mg; 1.05 mmol), and the resultant mixture was allowed to react for 4 hours at room temperature while being stirred. The solid formed by reaction was purified and separated through filtration, and dried under vacuum, to thereby yield 412 mg of bis(p-tert-butylphenyl)iodonium trifluoromethanesulfonate (yield: 76%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07335787B2 |
| Source dataset | uspto-grants-2008_02 |
| ORD ID | ord-32d5696a6e3a48849513a911fc87aa21 |
| Source note | uspto-grants-2008_02 |