HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2057514Generated: October 25, 2026
Sodium Acetate → 3-(2,2-Dichloroethenyl)-2,2-dimethylcyclopropane-1-carbonitrile
https://huagongshe.com/reaction/2057514
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | 4,6,6,6-Tetrachloro-2-cyano-3,3-dimethylhexanoic acid | HCID 20434843 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 3-(2,2-Dichloroethenyl)-2,2-dimethylcyclopropane-1-carbonitrile | HCID 12898173 | 97.3% |
Reaction Steps
4-Chloro-2-cyano-3,3-dimethyl-6,6,6-trichlorohexanoic acid (3.07 g) and sodium acetate (2.05 g; water-free) were dissolved in dimethyl formamide (8.0 ml). The solution was then stirred at 145° C. for 12 hours. The working-up procedure was the same as indicated in Example III and yielded 1.85 g of Compound A with purity 90%. Yield 86%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US04211720 |
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| Source dataset | uspto-grants-1980_07 |
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| ORD ID | ord-c3b5d3798f6a4b1d8a088b947a91d36d |
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| Source note | uspto-grants-1980_07 |
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