Boron trifluoride etherate → HCID 20330860, compound

HRID 2057561Notes

Reaction equation

HRID 2057561 reaction equation
B(F)(F)F.CCOCC.[Cl:10][C:11]1[C:16]2[C:17]3([CH2:29][O:28]3)[C:18]3[C:23]([C:24]4([CH2:26][O:25]4)[C:15]=2[CH:14]=[CH:13][CH:12]=1)=[C:22]([Cl:27])[CH:21]=[CH:20][CH:19]=3>C1(C)C=CC=CC=1>[Cl:10][C:11]1[C:16]2[CH:17]([CH:29]=[O:28])[C:18]3[C:23](=[C:22]([Cl:27])[CH:21]=[CH:20][CH:19]=3)[CH:24]([CH:26]=[O:25])[C:15]=2[CH:14]=[CH:13][CH:12]=1

Participants

4

Reactant 2

HCID 8000Boron trifluoride etherateHCID 86737085HCID 86737085, compound

Product 1

HCID 20330860HCID 20330860, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

To a solution of 0.1 ml. of boron fluoride etherate in 100 ml. of anhydrous toluene is added 500 mg. of 1',5'-dichloro-dispiro[oxirane-2,9'(10'H)-anthracene-10',2"oxirane]. The mixture is stirred at room temperature for 6 hours and filtered. The filtrate is washed twice with 10 ml. portions of a mixture of 10 ml. of saturated sodium bicarbonate and 10 ml. of ice water, dried over anhydrous sodium sulfate and filtered. The toluene is removed by water pump evacuation at 30° C. to give 0.5 g. of the desired product as a pale yellow solid, mp. 160°-172° C.

Workup

  1. filtrationfiltered
  2. washThe filtrate is washed twice with 10 ml
  3. additionportions of a mixture of 10 ml
  4. dry with materialof ice water, dried over anhydrous sodium sulfate
  5. filtrationfiltered
  6. customThe toluene is removed by water pump evacuation at 30° C.
  7. customto give 0.5 g

Sources & evidence

ORD record
ord-c9fcf3268bcf4eb28e24cc04fa9dea11
Source dataset
uspto-grants-1980_07
Patent number
US04211726

Reaction notes

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