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N-Phenylhydroxylamine → 1-(4-chlorophenyl)-N-phenylmethanimine oxide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | N-Phenylhydroxylamine | HCID 7518 | — |
| 反応物 | N-(p-Chlorobenzylidene)-2-methyl-4-chloroaniline | HCID 13017552 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | 1-(4-chlorophenyl)-N-phenylmethanimine oxide | HCID 254504 | — |
反応手順
N-phenylhydroxylamine (0.052 mole) was dissolved in ether (20 cc). This solution was treated with N-(p-chlorobenzylidene)-2-methyl-4-chloroaniline (13.8 g.) dissolved in ether (50 cc). After 15 min., white crystals had begun to form. Filtration and washing with ether gave α-p-chlorophenyl-N-phenylnitrone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04214003 |
| 出典データセット | uspto-grants-1980_07 |
| ORD ID | ord-86957667aefe49a7bddb51709e10b5bd |
| 出典メモ | uspto-grants-1980_07 |