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1,12-Dodecanediamine → N-[1-(Methylamino)-2-nitroethenyl]-1,12-dodecanediamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,12-Dodecanediamine | HCID 17727 | — |
| 反応物 | 1-Methylthio-1-methylamino-2-nitroethylene | HCID 123549 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | N-[1-(Methylamino)-2-nitroethenyl]-1,12-dodecanediamine | HCID 86737710 | 60% |
反応手順
A mixture of 1,12-diaminododecane (3 g) and N-methyl-1-(methylthio)-2-nitroethenamine (1.48 g) in water (50 ml) was stirred at room temperature for 20 hours. The solution was evaporated in vacuo and the residue chromatographed (silica/methanol). The appropriate eluate was evaporated to yield the title compound (1.8 g), mp. 123°-125°.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04317819 |
| 出典データセット | uspto-grants-1982_03 |
| ORD ID | ord-2024833d228846c7a2d74b0135140c60 |
| 出典メモ | uspto-grants-1982_03 |