関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | Diethylamine | HCID 8021 | — |
| 反応物 | Sodium 3-hydroxyacrylonitrile | HCID 86738287 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | 3-(Diethylamino)prop-2-enenitrile | HCID 54040110 | 63.5% |
反応手順
32.5 g (0.25 mol) of sodium-3-hydroxyacrylonitrile (content 70%) is added to a solution of 25.6 g (0.35 mol) of diethylamine, 21.0 g (0.35 mol) of acetic acid and 150 ml of acetonitrile, and the mixture is stirred for 16 h at 25° C. After working up as in Example 50, 19.7 g of 3-diethylaminoacrylonitrile was obtained (63.6%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04319024 |
|---|
| 出典データセット | uspto-grants-1982_03 |
|---|
| ORD ID | ord-790649635e9949e3bf62f63ea2d5c65b |
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| 出典メモ | uspto-grants-1982_03 |
|---|
