HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzylammonium chloride → 3-Benzylaminoacrylonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzylammonium chloride | HCID 2724127 | — |
| Reactant | Sodium 3-hydroxyacrylonitrile | HCID 86738287 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 3-Benzylaminoacrylonitrile | HCID 70548701 | 57.1% |
Reaction Steps
32.5 g (0.25 mol) of sodium-3-hydroxyacrylonitrile (content 70%) and 43.1 g (0.3 mol) of benzylamine hydrochloride are refluxed for 5 h in 150 ml of acetonitrile. After removal of the solid by filtration and withdrawal of the solvent, the product was dissolved in chloroform and washed with water. Subsequent vacuum distillation yielded 22.6 g of 3-benzylaminoacrylonitrile (57.1%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04319024 |
| Source dataset | uspto-grants-1982_03 |
| ORD ID | ord-0f57112ce6d9455cb4c8af2ad9496e10 |
| Source note | uspto-grants-1982_03 |