HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonic acid → HCID 13203357, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | 2,3-Dimercaptopropane | HCID 61217 | — |
| Reactant | 5-Hydroxyoctan-4-one | HCID 219794 | — |
| Product | HCID 13203357 | HCID 13203357 | — |
Reaction Steps
The method of Example 4 was followed, using butyroin (12 g), propane-1,2-dithiol (9 g) and p-toluenesulfonic acid (0.5 g). 2,3-Dihydro-2-methyl-5,6-dipropyl-1,4-dithiin was obtained as a greenish liquid, boiling range 76°-85°/0.055 mm, yield 7.5 g (35%). NMR (CDCl3) 0.92 δ (triplet), 1.25-2.4 δ (complex overlapping doublet, multiplet, and quartet) 2.6-3.6 δ (complex multiplet).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04319033 |
| Source dataset | uspto-grants-1982_03 |
| ORD ID | ord-8a4b7c6f306849a083010ce8bb896320 |
| Source note | uspto-grants-1982_03 |