HuagongsheHuagongshe Chemistry Print Report · For research reference only
p-Toluenesulfonic acid → 2,3,5,6,7,8-Hexahydro-1,4-benzodithiine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | p-Toluenesulfonic acid | HCID 6101 | — |
| Reactant | Cyclohexanone, 2-hydroxy- | HCID 10785 | — |
| Reactant | 1,1-Ethanedithiol | HCID 33645 | — |
| Product | 2,3,5,6,7,8-Hexahydro-1,4-benzodithiine | HCID 322903 | 75.1% |
Reaction Steps
The method of Example 4 was used, using 2-hydroxycyclohexanone (10 g), ethane dithiol (8.3 g) and p-toluenesulphonic acid to give 5,6,7,8-tetrahydro-1,4-benzodithian as a brownish oil (not distilled), yield 75.1%. NMR (CDCl3) 3.14 δ, 1.5-2.3 δ (two overlapping complex multiplets).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04319033 |
| Source dataset | uspto-grants-1982_03 |
| ORD ID | ord-f5bc392fd0ce4aeaa5585f0d5ee0f1da |
| Source note | uspto-grants-1982_03 |