Benzylaniline → HCID 13037489, compound

Participants

Reaction Steps

The procedure of Example 1 was employed utilizing N-benzylaniline and 4-methylthiophenyl phosphonic dichloride. The reaction of the dilithio compound and the 4-methylthiophenyl phosphonic dichloride was conducted at -76° C. to yield a beige solid. The beige solid was recrystallized from ethyl acetate to yield 1-(4-methylthiophenyl)-2-phenyl-2,3-dihydro-1H-2,1-benzazaphosphole-1-oxide (2.1 g, 11% yield) as a white solid having a melting point of 164°-167° C. and the following analysis:

Provenance & Evidence