HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzylaniline → 1-isopropyl-2-phenyl-2,3-dihydro-1H-2,1-benzazaphosphole-1-oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzylaniline | HCID 66028 | — |
| Reactant | Isopropylphosphonic dichloride | HCID 2793751 | — |
| Product | 1-isopropyl-2-phenyl-2,3-dihydro-1H-2,1-benzazaphosphole-1-oxide | HCID 13037491 | 11% |
Reaction Steps
The procedure of Example 1 was employed utilizing N-benzylaniline and isopropyl phosphonic dichloride. The reaction of the dilithio compound and the isopropyl phosphonic dichloride was conducted at -65° C. to yield 1-isopropyl-2-phenyl-2,3-dihydro-1H-2,1-benzazaphosphole-1-oxide (1.8 g, 11% yield) as a white solid having a melting point of 145°-147° C. and the following analysis:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04319913 |
| Source dataset | uspto-grants-1982_03 |
| ORD ID | ord-855b724bf20c4663b71e904a034327ca |
| Source note | uspto-grants-1982_03 |