Benzylaniline → HCID 13037505, compound

HRID 2058905Notes

Reaction equation

HRID 2058905 reaction equation
[CH2:1]([NH:8][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:15][C:16]1[CH:21]=[CH:20][C:19]([P:22](Cl)(Cl)=[O:23])=[CH:18][CH:17]=1>>[CH3:15][C:16]1[CH:21]=[CH:20][C:19]([P:22]2(=[O:23])[C:3]3[CH:4]=[CH:5][CH:6]=[CH:7][C:2]=3[CH2:1][N:8]2[C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:18][CH:17]=1

Participants

3

Reactant 2

HCID 66028BenzylanilineHCID 300865NSC176342

Product 1

HCID 13037505HCID 13037505, compoundYield 7%

Procedure

The procedure of Example 26 was employed utilizing N-benzylaniline and 4-methylphenyl phosphonic dichloride to yield 1-(4-methylphenyl)-2-phenyl-2,3-dihydro-1H-2,1-benzazaphosphole-1-oxide (0.65 g, 7% yield) as a white solid having a melting point of 180°-181° C. and the following analysis:

Sources & evidence

ORD record
ord-5d0398383b684c2183bd9a597a15a6db
Source dataset
uspto-grants-1982_03
Patent number
US04319913

Reaction notes

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