Chlorosuccinimide → HCID 59498104, compound

Participants

Reaction Steps

To a solution of 0.50 g (1.1 mmol) of phenyl 3,3-bis(phenylthio)-N-(phenyl)propanimidothioate in toluene (5 mL) was added 0.16 g (1.2 mmol) of N-chlorosuccinimide under ice cooling and stirred at room temperature for 3 hours. After dilution with t-butyl methyl ether (50 mL), the mixture was washed with saturated NaCl solution, dried over MgSO4, and concentrated under vacuum. The residue was purified by silica gel column chromatography (hexane:ethyl acetate=20:1) to obtain 38 mg of phenyl 3,3-bis(phenylthio)-N-phenyl-2-propenimidothioate (hereinafter referred to as the present compound 45).

Provenance & Evidence