4-Chlorotoluene → Tris(4-methylphenyl)sulfanium Chloride

HRID 2061307Notes

Reaction equation

HRID 2061307 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=O)=[CH:4][CH:3]=1.[Cl:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1>O>[Cl-:17].[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S+:8]([C:18]2[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=2)[C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 78104-ChlorotolueneHCID 15680p-Tolyl sulfoxide

Product 1

HCID 5351245Tris(4-methylphenyl)sulfanium Chloride

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The intended compound was obtained in a similar manner to that of Synthesis Example 1-1 except that bis(4-methylphenyl)sulfoxide was used instead of diphenylsulfoxide, 4-chlorotoluene was used instead of chlorobenzene, and the amount of water was increased at the time of extraction.

Workup

  1. customThe intended compound was obtained in a similar manner to that

Sources & evidence

ORD record
ord-4cd809fdc8f64979a4d946ae3dd3b2d7
Source dataset
uspto-grants-2012_10
Patent number
US08283104B2

Reaction notes

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