1-Bromo-4-tert-butylbenzene → Tris(4-tert-butylphenyl)sulfanium bromide

HRID 2061308Notes

Reaction equation

HRID 2061308 reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11]([C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=O)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[C:23]([C:27]1[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=1)([CH3:26])([CH3:25])[CH3:24]>O>[Br-:33].[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S+:11]([C:30]2[CH:31]=[CH:32][C:27]([C:23]([CH3:26])([CH3:25])[CH3:24])=[CH:28][CH:29]=2)[C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 775951-Bromo-4-tert-butylbenzeneHCID 184321184,4'-Sulfinylbis(tert-butylbenzene)

Product 1

HCID 23149384Tris(4-tert-butylphenyl)sulfanium bromide

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The intended compound was obtained in a similar manner to that of Synthesis Example 1-1 except that bis (4-tert-butylphenyl)sulfoxide was used instead of diphenylsulfoxide, 4-tert-butyl bromobenzene was used instead of chlorobenzene, and the amount of water was increased at the time of extraction.

Workup

  1. customThe intended compound was obtained in a similar manner to that

Sources & evidence

ORD record
ord-0c8dfe4cea5c4620a20654170e9a657a
Source dataset
uspto-grants-2012_10
Patent number
US08283104B2

Reaction notes

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