HuagongsheHuagongshe Chemistry Print Report · For research reference only
o-Bis(bromomethyl)benzene → HCID 10708125, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | o-Bis(bromomethyl)benzene | HCID 66665 | — |
| Reactant | Phenylsulphonylacetonitrile | HCID 82077 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Product | HCID 10708125 | HCID 10708125 | 27% |
Reaction Steps
Similarly to Example 1(a), by reaction of 5 g (27.6 mmol) of benzenesulfonyl-acetonitrile with 8 g (30.4 mmol) of a,a′-dibromo-o-xylene, 50 ml of aqueous soda solution, 629 mg (2.8 mmol) of benzyltriethylammonium chloride. 2.1 g of 2-benzenesulfonyl-indane-2-carbonitrile is obtained in the form of a white solid. (Yield=27%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08283378B2 |
| Source dataset | uspto-grants-2012_10 |
| ORD ID | ord-1598f56872f74c04a4358f0d0e7ca202 |
| Source note | uspto-grants-2012_10 |