Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Trimethyl borate | HCID 8470 | — |
| Reactant | Potassium Cyanide | HCID 9032 | — |
| Reactant | Trimethylsilyl cyanide | HCID 82115 | — |
| Product | Methoxytrimethylsilane | HCID 15771 | — |
| Product | Trimethylsilyl cyanide | HCID 82115 | — |
Reaction Steps
B(OCH3)3 (20.0 g, 0.19 mol) and KCN (12.5 g, 0.19 mol) were dissolved in TMSCN (66.8 g, 0.67 mol) and heated at a reflux temperature of 70° C. under protective gas for 18 hours. After cooling, all volatile components (unreacted TMSCN, formed TMSOMe) were distilled off to give powdery K[B(CN)3(OCH3)] in a yield of 27.8 g (92%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08283497B2 |
|---|
| Source dataset | uspto-grants-2012_10 |
|---|
| ORD ID | ord-ee02246b2a0240ba82b44e775374986d |
|---|
| Source note | uspto-grants-2012_10 |
|---|
