HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2063761Generated: November 2, 2026
tert-Butoxy bis(dimethylamino)methane → HCID 67406834, compound
https://huagongshe.com/reaction/2063761
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | tert-Butoxy bis(dimethylamino)methane | HCID 79885 | — |
| Reactant | 2-Cyclohexen-1-one, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]- | HCID 11746339 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 67406834 | HCID 67406834 | — |
Reaction Steps
A mixture of 2-(tert-butyl-dimethyl-silanyloxy)-cyclohex-2-enone (6.9 g, 30.48 mmol) in dry toluene (50 mL) was treated with Bredereck's reagent (9.44 ml, 45.72 mmol) was stirred at 115° C. for 24 hours. The mixture was concentrated under reduced pressure to give 2-(tert-butyl-dimethyl-silanyloxy)-6-dimethylaminomethylene-cyclohex-2-enone as a semi-solid brown residue which was used as such in the next step.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US08288400B2 |
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| Source dataset | uspto-grants-2012_10 |
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| ORD ID | ord-973fa032e94e4ceea85abf6958f4c01c |
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| Source note | uspto-grants-2012_10 |
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