HuagongsheHuagongshe Chemistry Print Report · For research reference only
Iodine → Triphenylphosphane diiodide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Iodine | HCID 807 | — |
| Reactant | Toluene | HCID 1140 | — |
| Reactant | Triphenylphosphine | HCID 11776 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Triphenylphosphane diiodide | HCID 21889549 | — |
Reaction Steps
A suspension of iodine (13.0 g, 51 mmol) and toluol (100 mL) was heated with reflux for 20 min. The solution formed was cooled to room temperature and added in drops to a solution of triphenylphosphine (14.0 g, 53 mmol) in anhydrous diethyl ether (100 mL). The separated yellow precipitate was filtered off and washed with diethyl ether.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08288430B2 |
| Source dataset | uspto-grants-2012_10 |
| ORD ID | ord-c873f969ddbd4aa5883f973d2fe23cf0 |
| Source note | uspto-grants-2012_10 |