HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dibenzylamine → HCID 5368605, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dibenzylamine | HCID 7656 | — |
| Reactant | Ethylacetate heptane | HCID 21899848 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 5368605 | HCID 5368605 | 70% |
Reaction Steps
Reaction of 30 (rac-Ethyl (2E)-4-(chloroacetoxy)pent-2-enoate) (221 mg, 1.0 mmol) with Bn2NH (383 μL, 2.0 mmol) and 8 mol % [Pd] in CH2Cl2 (10 ml) at room temperature according to Example 2. Flash chromatography (AcOEt heptane fraction 5:95) yields 12 (rac-Ethyl (2E)-N,N-dibenzyl-4-aminopent-2-enoate) (227 mg, 70%) as a colorless oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08288566B2 |
| Source dataset | uspto-grants-2012_10 |
| ORD ID | ord-60fd55268e5141b3b6ff100415ecc3b9 |
| Source note | uspto-grants-2012_10 |