Tris(pentafluorophenyl)borane → HCID 12509143, compound

HRID 2070217Notes

Reaction equation

HRID 2070217 reaction equation
[C:1]1([N:7]2[C@H:9]([C:10]3[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=3)[C@@H:8]2[C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.B(C1C(F)=C(F)C(F)=C(F)C=1F)(C1C(F)=C(F)C(F)=C(F)C=1F)C1C(F)=C(F)C(F)=C(F)C=1F>>[C:16]1([CH:8]([NH:7][C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH2:9][C:10]2[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=2)[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=1

Participants

3

Reactant 2

HCID 582056Tris(pentafluorophenyl)boraneHCID 1550757cis-1,2,3-Triphenylaziridine

Product 1

HCID 12509143HCID 12509143, compound

Procedure

In a glovebox, cis-1,2,3-triphenylaziridine (1 mmol), B(C6F5)3 (6.05 mmol) and (2,4,6-Me3C6H2)3P (0.05 mmol) are reacted according to the procedure of the Comparative Example to yield N-1,2-diphenylethyl-N-phenyl amine.

Sources & evidence

ORD record
ord-60f19a68920148d8b4d1e8a157e05225
Source dataset
uspto-grants-2012_10
Patent number
US08299284B2

Reaction notes

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