Carbon Disulfide → N-(4-Aminophenyl)hydrazinecarbothioamide

Participants

Reaction Steps

As per general procedure (9) except with benzene-1,4-diamine (2.16 g, 20.00 mmol), CS2 (1.20 mL, 20.00 mmol), NaOH (0.80 g, 20.00 mmol), sodium chloroacetate (2.33 g, 20.00 mmol) and NH2NH2 (5.60 mL, 0.18 mol). The product was isolated as a cream solid (1.37 g, 38%). 1H NMR: δ 4.65 (2H, s, PhNH2); 4.95 (2H, s, NHNH2); 6.49 (2H, d, J 8.65, 3-ArH); 7.08 (2H, d, J 8.30, 2-ArH); 8.80 (1H, s, NH); 9.25 (1H, s, NHNH2).

Provenance & Evidence