HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → Ethanethiol, 2-(phenylmethoxy)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | S-2-(benzyloxy)ethyl ethanethioate | HCID 86045393 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Ethanethiol, 2-(phenylmethoxy)- | HCID 14571805 | 97.4% |
Reaction Steps
Potassium carbonate (11.20 g) was added to S-2-(benzyloxy)ethyl ethanethioate (8.52 g) in methanol (170 mL)/water (85 mL) and the reaction was stirred for 20 min. Water was added and the mixture extracted with ethyl acetate. The organic layers were combined, washed with aqueous ammonium chloride and dried (MgSO4) and concentrated in vacuo to give the subtitle compound (6.64 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08299246B2 |
| Source dataset | uspto-grants-2012_10 |
| ORD ID | ord-948da48b2e9540c5818f76773d95046e |
| Source note | uspto-grants-2012_10 |