HRID2071226

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID22397602

2,2,6,6-Tetramethylpiperidin-4-one--water (1/1)

C9H19NO2

HCID178479531

未命名化合物

PRODUCTS

生成物

结构：CC1(C)CC(=NNC(=N)NN=C2CC(C)(C)NC(C)(C)C2)CC(C)(C)N1.Cl

HCID177725582

未命名化合物

收率 50%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID702

Ethanol

C2H6O

CONDITIONS

反应条件

温度: 25 °C

PROCEDURE

实验过程

A solution of diaminoguanidine hydrochloride (6.28 grams; 0.05 mole) and 2,2,6,6-tetramethyl-4-piperidone monohydrate (17.3 grams; 0.10 mole) in 200 mls. of ethanol 2B was refluxed for a period of 15 hours while stirring. The resulting slurry was cooled to 25° C. and the solid was separated to obtain 10.0 grams of crude 1,3-bis[(2,2,6,6-tetramethyl-4-piperidylidene)amino]guanidine hydrochloride. Recrystallization of the crude hydrochloride from ethanol 2B gave 8.9 grams of white solid, m.p. 210°-220° C. (dec).

WORKUP

后处理

customthe solid was separated