HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → P-Toluic Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Ethylene | HCID 6325 | — |
| Reactant | Ethylene Oxide | HCID 6354 | — |
| Reactant | P-Xylene | HCID 7809 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | P-Toluic Acid | HCID 7470 | — |
| Product | 4-Methylbenzaldehyde | HCID 7725 | — |
| Product | 4-Methylbenzyl alcohol | HCID 11505 | — |
Reaction Steps
Into a pressure vessel equipped with magnetic agitation is placed a charge that at the reaction temperature of 205° C. is composed of about 2.9 wt.% ethylene, 55.9 wt.% p-xylene, 41.1 wt.% benzene at a partial pressure of oxygen of 60 p.s.i.a. and a system pressure of 1125 p.s.i.g. The reaction mixture is reacted for 10 min. Analysis of the liquid phase effluent shows that 1.26 wt.% ethylene oxide has been produced as well as 1.0 wt.% p-tolualdehyde, 1.5 wt.% p-methyl benzyl alcohol moieties, and 0.75 wt.% p-toluic acid moieties.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04046782 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-2b781ba06bb64ceda1e289469c7cfa43 |
| Source note | uspto-grants-1977_09 |