2-Bromobutane → HCID 22393739, compound

HRID 2071322Notes

Reaction equation

C(Br)(CC)C.[CH:6]([CH:10]([C:13]1[CH:22]=[CH:21][C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=1)[C:11]#[N:12])([CH2:8]C)[CH3:7]>>[CH:6]([CH:10]([C:13]1[CH:22]=[CH:21][C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=1)[C:11]#[N:12])([CH3:8])[CH3:7]

Participants

Reactant 2

HCID 65542-Bromobutane

HCID 20395159alpha-Sec-butyl-2-naphthaleneacetonitrile

Product 1

HCID 22393739HCID 22393739, compound

Procedure

This procedure is repeated in all essential details excepting that isobutyl bromide (1-bromo-2-methylpropane) is substituted for 2-bromopropane. This latter procedure yields α-isobutyl-2-naphthaleneacetonitrile. When the procedure is repeated with sec-butylbromide the corresponding α-sec-butyl-2-naphthaleneacetonitrile is obtained.

Workup

customis obtained

Sources & evidence

ORD record: ord-cfa24c0b5cec414481e0d5cfddf5f699
Source dataset: uspto-grants-1977_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04046799

Reaction notes

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