HuagongsheHuagongshe Chemistry Print Report · For research reference only
Brucine → HCID 18594875, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Brucine | HCID 442021 | — |
| Reactant | HCID 18594802 | HCID 18594802 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | HCID 18594875 | HCID 18594875 | — |
Reaction Steps
A 1.06 g. sample of ethyl 15-azido-9-oxo-prostanoate (Example 110) is hydrogenated using 100 mg. of 5% palladium on carbon in 50 ml. absolute alcohol for 16 hours. The filtration of the catalyst and evaporation of the solvent affords an oil. Silica gel chromatography gives 604 mg. of oil; λ max. 2.95, 6.30 (brucine) and 5.72 μ (carbonyl groups).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04046787 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-f60c3c552dfc4ed5aa1086a1177ae164 |
| Source note | uspto-grants-1977_09 |