HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → Dimethyl 3-(3-chlorophenoxy)-2-oxopropylphosphonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | Dimethyl 3-(3-chlorophenoxy)-2-semicarbazonopropylphosphonate | HCID 54268141 | — |
| Reactant | Dimethyl 3-(3-chlorophenoxy)-2-oximinopropylphosphonate | HCID 73676786 | — |
| Solvent | Toluene | HCID 1140 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Dimethyl 3-(3-chlorophenoxy)-2-oxopropylphosphonate | HCID 3566446 | — |
Reaction Steps
The process described in Example 1 was repeated, using a solution in toluene of dimethyl 3-(3-chlorophenoxy)-2-oximinopropylphosphonate in place of the solution in toluene of dimethyl 3-(3-chlorophenoxy)-2-semicarbazonopropylphosphonate, to give dimethyl 3-(3-chlorophenoxy)-2-oxopropylphosphonate, RF = 0.29 (ethyl acetate), RF = 0.58 (5% v/v methanol in methylene dichloride).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04046841 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-e5295967ad1f421abbb25120c93fcaf1 |
| Source note | uspto-grants-1977_09 |