HuagongsheHuagongshe Chemistry Print Report · For research reference only
5-Methyl-2-pyrrolidone → 10-(2-Methyl-3,4-dihydro-2H-pyrrol-5-yl)-10H-phenoxazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 5-Methyl-2-pyrrolidone | HCID 66055 | — |
| Reactant | Phenoxazine | HCID 67278 | — |
| Product | 10-(2-Methyl-3,4-dihydro-2H-pyrrol-5-yl)-10H-phenoxazine | HCID 22754255 | — |
Reaction Steps
Reaction of phenoxazine with 5-methyl-2-pyrrolidinone according to the procedure of Example 1 affords the free base 10-(5-METHYL-1-PYRROLIN-2YL)PHENOXAZINE, m.p. 135°-137° C., from n-heptane. Conversion of the free base to the hydrochloride salt provides 10-(5-METHYL-1-PYRROLIN-2YL)PHENOXAZINE HYDROCHLORIDE, m.p. 229.5°-236.0° C. (dec.) (corr.), in a 57% overall yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04046891 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-e0c6b224581e4d11b75bfffb932fd6e7 |
| Source note | uspto-grants-1977_09 |