HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 21413954, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | Ethyl 2-bromohexadecanoate | HCID 12385850 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 21413954 | HCID 21413954 | — |
Reaction Steps
To a solution of sodium ethoxide in ethanol, prepared from sodium (1.46 g) and ethanol (35 ml) a solution of ethyl 2-bromohexadecanoate (20.3 g) in ethanol (25 ml) was added. After refluxing for 3 h water was added and the product was taken up in ether. After evaporation of the ether and fractionation of the residue there was obtained 10.8 g ethyl 2-ethoxyhexadecanoate b.p. 112°-114° (0.01 mm), nD23 1.4393.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04046914 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-9781135e08ef48189c37f7aa451d05eb |
| Source note | uspto-grants-1977_09 |