HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,1-Bis(methylthio)-2-nitroethylene → 1-Nitro-2-methylthio-2-[3-(2-oxazolylthio)propylamino]ethylene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,1-Bis(methylthio)-2-nitroethylene | HCID 83623 | — |
| Reactant | 2-(3-Aminopropyl)thiooxazole | HCID 20550119 | — |
| Product | 1-Nitro-2-methylthio-2-[3-(2-oxazolylthio)propylamino]ethylene | HCID 70541392 | 63% |
Reaction Steps
By the procedure of Example 8(i), 2-(3-aminopropylthio)oxazole (2.1 g) is reacted with 1-nitro-2,2-bis-methylthioethylene (2.0 g) to give 1-nitro-2-methylthio-2-[3-(2-oxazolylthio)propylamino]ethylene (2.1 g) which, on reaction with methylamine by the procedure of Example 8(ii) gives the title product (1.8 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04046907 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-a8feae3ee3f14df8967de861546cd7cf |
| Source note | uspto-grants-1977_09 |