Back
HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 2071893Generated: October 31, 2026

Sulfur Dioxide → Imidodisulfuric acid, N-hydroxy-, sodium salt (1:2)

https://huagongshe.com/reaction/2071893

Reaction equation

Participants

RoleNameHCIDCharge
ReactantSulfur DioxideHCID 1119—
ReactantHydroxylamine, sulfate (1:1)HCID 159255—
ReactantSodium BisulfiteHCID 23665763—
ReactantSodium NitriteHCID 23668193—
ProductImidodisulfuric acid, N-hydroxy-, sodium salt (1:2)HCID 169269—

Reaction Steps

One suitable technique for preparing hydroxylamine sulfate is the classical Raschig process, described in Kirk-Othmer, Vol. 7 (1951), page 766, paragraph 4, Briefly, the classical Raschig process involves the reduction of sodium nitrite with sodium bisulfite and sulfur dioxide to give sodium hydroxylamine -N, N-disulfonate, followed by hydrolysis of the hot solution to give hydroxylammonium acid sulfate.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04049646
Source datasetuspto-grants-1977_09
ORD IDord-ad25aac9584c441e88e2e2319e0a8aec
Source noteuspto-grants-1977_09