Methanol → HCID 70600924, compound

HRID 2072234Notes

Reaction equation

HRID 2072234 reaction equation
C([O:4][C:5]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)([CH3:9])[CH2:6][CH2:7][OH:8])(=O)C.[OH-].[K+].CO.O>C(Cl)(Cl)Cl>[C:11]1([C:16]2[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=2)[CH:12]=[CH:13][CH:14]=[CH:15][C:10]=1[C:5]([OH:4])([CH3:9])[CH2:6][CH2:7][OH:8]

Participants

6

Reactant 4

HCID 887MethanolHCID 962WaterHCID 14797Potassium HydroxideHCID 70601037HCID 70601037, compound

Product 1

HCID 70600924HCID 70600924, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

2.84 g. of 3-acetoxy-3-p-biphenylyl-1-butanol are boiled for 2 hours with 2 g. of KOH in 50 ml. of methanol, water and chloroform are added and the mixture is worked up to give 3-p-biphenylyl-1,3-butanediol, m.p. 115°-117°.

Sources & evidence

ORD record
ord-3c8335929c384737bf0da837cb390798
Source dataset
uspto-grants-1977_09
Patent number
US04049823

Reaction notes

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