HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → HCID 70634840, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | Lithium Chloride | HCID 433294 | — |
| Reactant | HCID 70634888 | HCID 70634888 | — |
| Catalyst | tungsten carbide (WC) | HCID 25504 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 70634840 | HCID 70634840 | — |
Reaction Steps
1.0 g. of 3-methoxy-17-ethylenedioxy-1,3,5(10)-estratriene in 10 ml. of ethanol is added to 200 ml. of liquid ammonia, 2 g. of lithium chloride, and electrolyzed for 1 hour at 1 ampere on a tungsten carbide electrode in a cell divided by a cation exchanger membrane. After the mixture has been worked up, 0.9 g. of 3-methoxy-17-ethylenedioxy-2,5(10)-estradiene is produced, m.p. 115°-120° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04050998 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-aa4dd07841974b40940c3a79bd43abba |
| Source note | uspto-grants-1977_09 |