HCID 12923316, compound → 2-Methyl-3-tert.-butoxypropan-1-ol

HRID 2072348Notes

Reaction equation

HRID 2072348 reaction equation
[C:1]([O:5][CH2:6][CH:7]([CH3:15])[C:8](OC(C)(C)C)=[O:9])([CH3:4])([CH3:3])[CH3:2].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[C:1]([O:5][CH2:6][CH:7]([CH3:15])[CH2:8][OH:9])([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 2

HCID 12923316HCID 12923316, compoundHCID 21226445Aluminium lithium hydride

Product 1

HCID 125367792-Methyl-3-tert.-butoxypropan-1-olYield 88%

Procedure

Reduction of rac.-tert. butyl 3-tert. butoxy-2-methyl-propionate was carried out with lithium aluminum hydride using the procedure described in Example 2. The resulting rac.-3-tert. butoxy-2-methyl-1- propanol was obtained in 88% yield as a colorless liquid, b.p. 70°-72° C. (10 mm Hg.).

Sources & evidence

ORD record
ord-1ef0d9867573417797988754ffb925ae
Source dataset
uspto-grants-1977_09
Patent number
US04051153

Reaction notes

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