HuagongsheHuagongshe Chemistry Print Report · For research reference only
(R)-(+)-4-tert. butoxy-3-methyl-1-butanol → 4-methylbenzenesulfonic acid;(3R)-3-methyl-4-[(2-methylpropan-2-yl)oxy]butan-1-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (R)-(+)-4-tert. butoxy-3-methyl-1-butanol | HCID 86735110 | — |
| Reactant | (R)-(+)-4-tert. butoxy-3-methyl-1butanol p-toluenesulfonate | HCID 131710899 | — |
| Product | 4-methylbenzenesulfonic acid;(3R)-3-methyl-4-[(2-methylpropan-2-yl)oxy]butan-1-ol | HCID 86735111 | 90% |
Reaction Steps
Using the procedure of Example 8, (R)-(+)-4-tert. butoxy-3-methyl-1-butanol was converted into (R)-(+)-4-tert. butoxy-3-methyl-1-butanol p-toluenesulfonate which was isolated in 90% yield as a pale yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04051153 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-913138e35cde411b85f58d53daeedee6 |
| Source note | uspto-grants-1977_09 |