HuagongsheHuagongshe Chemistry Print Report · For research reference only
(R)-(+)-4-tert. butoxy-3-methyl-1butanol p-toluenesulfonate → (R)-(+)-1-tert. Butoxy-2,6-dimethylheptane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | (R)-(+)-4-tert. butoxy-3-methyl-1butanol p-toluenesulfonate | HCID 131710899 | — |
| Reactant | HCID 178418816 | HCID 178418816 | — |
| Product | (R)-(+)-1-tert. Butoxy-2,6-dimethylheptane | HCID 13206259 | 76% |
Reaction Steps
Coupling of (R)-(+)-4-tert. butoxy-3-methyl-1butanol p-toluenesulfonate with isobutylmagnesium bromide was carried out using the procedure of Example 47. (R)-(+)-1-tert. Butoxy-2,6-dimethylheptane was obtained in 76% yield as a colorless liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04051153 |
| Source dataset | uspto-grants-1977_09 |
| ORD ID | ord-44f0d648d2414e618c16fa7d219a2cd8 |
| Source note | uspto-grants-1977_09 |